A pipette is one of the most commonly used precision liquid transfer tools in the laboratory, mainly used to accurately transfer a certain volume of liquid. Correctly reading the scale and operating the pipette are key to ensuring experimental accuracy. This article details the types of pipettes, scale reading methods, usage steps, and precautions.

💡 Key Point

The scale reading method of a pipette varies by type: drain-out pipettes have scales with "0" at the top and the maximum scale at the bottom; after the liquid drains naturally, do not blow out the residual liquid in the tip. Blow-out pipettes are marked "Blow out" on the barrel, and the residual liquid in the tip must be blown out.

1. Types and Selection of Pipettes

According to structure and purpose, pipettes are mainly divided into the following categories:

1.1 Classification by Structure

1.2 Classification by Scale Orientation

Type Scale Orientation Reading Method Blow out?
Drain-out (Top scale) 0 at top, max scale at bottom Lowest point of meniscus at scale ❌ Do not blow
Blow-out (Bottom scale) 0 at bottom, max scale at top Lowest point of meniscus at scale ✅ Blow out
Volumetric Pipette Only one calibration line Meniscus tangent to calibration line Depends on marking

1.3 Common Specifications

Common pipette specifications in the laboratory include: 0.1mL, 0.2mL, 0.5mL, 1mL, 2mL, 5mL, 10mL, 25mL, 50mL, etc. For experiments with high precision requirements, it is recommended to choose a volumetric pipette; for experiments requiring flexible adjustment of transfer volume, choose a graduated pipette.

2. How to Read a Pipette Scale? Key Techniques

Correctly reading the pipette scale is the basis for accurate liquid transfer. The following are detailed steps and precautions:

1Ensure the pipette is vertical

When reading the scale, the pipette must be kept vertical; it must not be tilted, otherwise the liquid level will shift, causing reading errors.

2Eye level with the liquid surface

Your line of sight must be horizontal with the liquid surface. Looking down from above will make the reading larger; looking up from below will make the reading smaller.

3Read the lowest point of the meniscus

The liquid forms a concave meniscus inside the pipette. For transparent liquids (such as water, transparent solutions), read the scale corresponding to the lowest point of the concave meniscus. For dark or opaque liquids, read the highest point of the liquid surface.

4Use a background contrast

To observe the meniscus more clearly, you can place a white paper behind the pipette as a background, so that the meniscus will be seen more clearly.

⚠️ Common Mistakes

1. Eye not horizontal: Looking down makes the reading larger; looking up makes the reading smaller. The error can reach 2%~5%.
2. Reading the highest point of the meniscus: For transparent liquids, read the lowest point. Reading the highest point will make the transferred volume larger.
3. Pipette tilted: Tilting will cause the liquid level to shift, resulting in inaccurate readings.

3. Correct Pipette Usage Steps

Step 1: Choose the right pipette

According to the volume of liquid to be transferred, select the pipette with the closest range. For example, if you need to transfer 9.5mL of liquid, you should choose a 10mL pipette, not a 25mL pipette, because the closer the range, the higher the precision.

Step 2: Rinse the pipette

Use the liquid to be transferred to rinse 2~3 times. The method is: suck in a small amount of liquid, slowly tilt and rotate the pipette to let the liquid wet the inner wall, then discharge from the tip. This prevents concentration changes caused by adsorption on the tube wall.

Step 3: Suck in the liquid

Insert the pipette into the liquid (depth about 1cm), use a rubber bulb (must not suck directly with the mouth!) to slowly suck the liquid, so that the liquid level rises to about 1~2cm above the scale line.

Step 4: Adjust the liquid level to the scale

Quickly use the index finger (or thumb) to block the upper end of the pipette, then slowly relax the finger, so that the liquid level slowly drops until the lowest point of the meniscus is tangent to the scale line. At this point, stop relaxing the finger and keep the liquid level stable.

Step 5: Discharge the liquid

Rest the pipette tip against the inner wall of the receiving container (tilted about 45°), and discharge the liquid naturally. For drain-out pipettes, after the liquid stops flowing, wait 3~5 seconds to let the residual liquid in the tip flow out naturally (or along the wall). Do not blow out. For blow-out pipettes, you need to blow out the residual liquid in the tip.

📜 Special Tip

When discharging liquid from a pipette, the tip should rest against the container wall, not suspended in the air, otherwise the liquid will flow down the outer wall, causing inaccurate transfer volume. At the same time, the container should be tilted about 45° to facilitate liquid inflow.

4. Precautions for Pipette Use

5. Choosing Between Pipette and Pipettor

In modern laboratories, pipettors are becoming increasingly popular. When to use a pipette and when to use a pipettor?

Comparison Item Pipette Pipettor
Precision High (Class A: ±0.2%~0.8%) Relatively high (±0.5%~3%)
Volume Range 0.1mL~50mL (larger volumes need graduated cylinder) 0.5μL~10mL
Ease of Operation Requires rubber bulb, more cumbersome to operate One-handed operation, very convenient
Suitable Scenarios Large volume transfer, standard solution transfer Small volume transfer, PCR, cell experiments
Cost Low (glass pipettes can be reused) High (pipettor price is higher)

Summary: When the transfer volume is > 1mL and the precision requirement is high, priority is given to the pipette; when the transfer volume is < 1mL or high-throughput operation is required, priority is given to the pipettor.

6. Frequently Asked Questions (FAQ)

❓ Should the residual liquid in the pipette tip be blown out?
This depends on the type of pipette. If it is a drain-out pipette (scales marked at the top, 0 at the top), the residual liquid in the tip must not be blown out because this portion of volume is already accounted for in the calibration. If it is a blow-out pipette (marked "Blow out" or "Blow-out" on the barrel), then blow out the residual liquid in the tip. Before use, carefully check the markings on the pipette barrel.
❓ Why is pipette rinsing important?
The inner wall of the pipette will adsorb a small amount of liquid. If not rinsed, the first sucked liquid will be partially adsorbed by the tube wall, causing the concentration to become higher. Rinsing 2~3 times can saturate the tube wall adsorption and ensure the concentration of subsequent transfers is accurate. Rinsing should use the same liquid to be transferred; do not rinse with water.
❓ Why use a white paper background when reading pipette scales?
The liquid forms a meniscus inside the pipette, and the meniscus of transparent liquid may not be very clear. Placing white paper behind the pipette can increase contrast, making the meniscus clearer and easier to read, reducing reading errors. This is a simple but very effective technique.
❓ Can pipettes be heated?
Ordinary glass pipettes are not recommended for direct heating because heating will cause glass expansion, affecting scale accuracy, and may even cause breakage. If you need to heat the liquid, you should first heat the liquid in another container to the required temperature, cool to room temperature, and then use the pipette to transfer. Heat-resistant quartz pipettes can be used within a certain temperature range, but attention must also be paid to the effect of temperature on volume.
❓ What is the difference between Class A and Class B pipettes?
Class A pipettes have higher precision and smaller volume errors (for example, a 25mL Class A pipette has an error of ±0.03mL, while Class B is ±0.06mL). For standard experiments and quantitative analysis, Class A should be prioritized; Class B pipettes have lower precision and are suitable for experiments or teaching experiments that do not require high precision. Class A pipettes are usually more expensive, but have a better cost-performance ratio (because they can reduce the probability of experiment failure).